You can now make video calls to the iPhone, and it has written several about. Now I have tried it also and it is through free program Fring. Now it is only on call for iPhone, for all that happens is that I can see it as making a Skype video call to me. The condition is that the caller has webcam (of course) and Skype and I have Iphone connected via W-LAN. It does not work when you only have 3G connectivity.
Do you not Fring already so I can tell you that there is a program, except for Skype also allows you to chat via MSN Messenger, Google Talk, AIM and many others. In addition, the notifications, so you can stay online without having the program up and active.
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